Argiano is thought to be an ancient place, full of history, where wise men searched for Ara Jani, the legendary altar of the roman god Janus.
At the summit of a wonderful hill, south-west of Montalcino, the magnificent Villa of Argiano was built in the Renaissance by the Peccis, a noble family from Siena.
Remaining for some decades under the Pecci family, it then passed to the counts of Pieri, who bequeath it to the marquis of Ballanti Merli and to the duchess of Caetani from the counts Lovatelli. In 1992, it was acquired by the countess Noemi Marone Cinzano.